Explain The Polymerization Of Vinyl Chloride

Polyvinyl chloride is produced by polymerizationof the vinyl chloridemonomer vcm as shown.

Explain the polymerization of vinyl chloride.

Following its generation the initiating free radical adds nonradical monomer units thereby growing the polymer chain. For efficient cationic polymerization of vinyl monomers it is necessary that the carbon carbon double bond be the strongest nucleophile in the molecule. Molecular weights of the polymers have b. Emulsion polymerization accounts for about 12 and bulk polymerization accounts for 8.

About 80 of production involves suspension polymerization. The reactants are then heated in the closed system to about 50 c and the pressure rises to about 0 5 mpa. Pvc is used in the manufacture of numerous products including packaging films and water pipes. A typical polymerization includes 180 parts water and 100 parts vinyl chloride monomer chain transfer agent trichloro ethylene.

Definition of vinyl type polymerization. Addition polymerization of vinyl compounds or related unsaturated compounds as vinylidene chloride. About 80 of production involves suspension polymerization. Other surfactant molecules clump together into smaller aggregates called micelles which also absorb monomer molecules.

The surfactant molecules composed of a hydrophilic water attracting and hydrophobic water repelling end form a stabilizing emulsion before polymerization by coating the monomer droplets. The polymerization of vinyl chloride has been studied dilatometrically in chlorobenzene using azoisobutyronitrile as an initiator at temperatures between 30 and 45 c and with monomer and initiator concentrations varying from 1 0 to 8 1 m and from 0 005 to 0 1 m respectively. Polymerization of vinyl chloride vc was studied. Natural evolution of hcl from vc occurred in the polymerization.

When treated with certain catalysts vinyl chloride monomers undergo polymerization and form the larger compound known as polyvinyl chloride or pvc. Pvc vinyl chloride is an organohalogen compound that has important industrial applications. Free radical polymerization frp is a method of polymerization by which a polymer forms by the successive addition of free radical building blocks. Emulsion polymerizationaccounts for about 12 and bulk polymerizationaccounts for 8.

Thus vinyl acetate would be classed as an electron donor type monomer section 9 10 2 but it cannot be polymerized cationically because the carbonyl group complexes the active center.